The d-alpha form of Vitamin E is the natural form. The dl-alpha form of Vitamin E is synthetic. Any “-acetate” form of Vitamin E is useless at preventing oxidation in your actual formulation. The d-alpha form of Vitamin E is best for your actual skin.
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Keep your Vitamin E below 2% in your formula. Even 0.1% mixed tocopherols (MT) can help prevent oxidation longer in your actual formulation.